Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.
نویسندگان
چکیده
Iron-catalyzed trifluoromethylation with concomitant 1,2-migration of an aryl group starting from diaryl allyl alcohol was achieved under mild conditions. This reaction system affords α-substituted-β-trifluoromethyl carbonyl compounds in high efficiency. In the case of substrates bearing different aryl groups, selective migration was observed.
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عنوان ژورنال:
- Chemical communications
دوره 49 66 شماره
صفحات -
تاریخ انتشار 2013